Abstract
Additive schemes for calculating the molar volumes and heats of vaporization of liquid alkanes from increments characteristic of the numbers and different types of carbon atoms (primary, secondary, tertiary, quaternary), of the mole fraction Zg of gauche conformations, and (where necessary) of other steric factors have been developed. It is suggested that schemes for correlating physical properties of alkanes with connectivity indices mχt are successful because these indices are also correlated with numbers and types of carbon atoms and with Zg.
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