Abstract
The reaction of phosgene with copper between 260° and 400°C leads to the formation of cuprous chloride . The rate law is of the paralinear type with a pressure influence especially during the parabolic stage. It was shown that, with our experimental conditions, the gaseous phase is always far from equilibrium. A mechanism accounting for the observed rate law is proposed. It involves simultaneously three rate‐determining steps: the adsorption of phosgene, the adsorption of carbon monoxide, and the outer interfacial reaction.
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