Abstract
The reaction of phosgene with copper between 260° and 400°C leads to the formation of cuprous chloride . The rate law is of the paralinear type with a pressure influence especially during the parabolic stage. It was shown that, with our experimental conditions, the gaseous phase is always far from equilibrium. A mechanism accounting for the observed rate law is proposed. It involves simultaneously three rate‐determining steps: the adsorption of phosgene, the adsorption of carbon monoxide, and the outer interfacial reaction.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
