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https://doi.org/10.1246/cl.1992.339
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Cite Journal: Chemistry Letters |  Publication Date: Feb 1, 1992 |
 Citations: 30 |
Affiliation: Tohoku University
Abstract Both cyclic and acyclic acetylenes substituted by two silyl groups on each end undergo facile 1,2-silyl shift in the reaction with cyclopentadienyltricarbonylmanganese under photochemical conditions to give 2,2-disilylvinylidene complexes. Several interesting reactions of the novel complexes are described.
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