Abstract
Polymeric precursors to ceramics have the potential to enable production of ceramic articles in novel forms, with novel microstructures, and improved properties. The polymer-to-ceramic conversion process is not sufficiently understood for this approach to be widely utilised. Perhydropolysilazane converts to high purity silicon nitride (Si 3N 4), and has been shown to be a useful coating and matrix precursor. The conversion of PHPS to Si 3N 4 is being examined by Solid State, Magic Angle Spinning (MAS) NMR spectroscopy and other techniques. This paper summarises the results to date of this investigation.
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