The primary stages of polyoxomolybdate catalyzed cyclohexanone oxidation by hydrogen peroxide as investigated by in situ NMR. Substrate activation and evolution of the working catalyst

Dahbia Amitouche,Mohamed Haouas,Tassadit Mazari,Sihem Mouanni,Romain Canioni,Chérifa Rabia,Emmanuel Cadot,Catherine Marchal-Roch

doi:10.1016/j.apcata.2018.05.017

The primary stages of polyoxomolybdate catalyzed cyclohexanone oxidation by hydrogen peroxide as investigated by in situ NMR. Substrate activation and evolution of the working catalyst

Dahbia Amitouche, Mohamed Haouas + Show 6 more

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https://doi.org/10.1016/j.apcata.2018.05.017

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Journal: Applied Catalysis A, General	Publication Date: May 23, 2018
Citations: 18

Affiliation: Institut Lavoisier de Versailles, University of Paris-Saclay, Institut Polytechnique de Paris, French National Centre for Scientific Research, University of Sciences and Technology Houari Boumediene, Mouloud Mammeri University of Tizi-Ouzou

#Real Working Conditions #Cyclohexanone Oxidation + Show 8 more

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Abstract

ABSTRACT The catalytic process of cyclohexanone oxidation by hydrogen peroxide was investigated using in situ NMR spectroscopy in real working conditions. The behavior of the Keggin heteropolyacid H3PMo12O40, used as a model catalyst, was explored before and after adding the oxidant agent. This study revealed the evolution pathways to different reduced states of H3PMo12O40 and its reversible transformation into peroxomolybdate complexes. These latter were identified as the active species for the adipic acid formation, while the acid function of the catalyst was found important for the substrate activation via ketonic-enolic tautomerism. The oxidative mechanism of the cyclohexanone was described through three successive steps to produce adipic acid.

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