The preparation of CaCO3-polyalkoxysilane porous nanocomposites as effective sorbent for oil spill removal.

Abstract

The novel porous nanocomposite sorbent was synthesized by the condensation of the diol monomer with the alkoxysilane cross-linker at moderately high temperatures in the presence of nano-CaCO3 particles. The structural, thermal, and morphological properties of the nanocomposite sorbents were determined by using Fourier transform infrared spectroscopy (FTIR), solid-state CPMAS 13C and 29Si NMR,scanning electron microscope (SEM), and thermal gravimetric analysis (TGA). Adding nano-CaCO3 to the network structure of the polymer not only provided pores to the sorbent but also enhanced its sorption capacity towards various oils and toxic organic solvents. The nanocomposite sorbent exhibited excellent absorption capacity for different toxic organic solvents and oils and great reusability for ten cycles. Moreover, the obtained sorbent material selectively absorbed organic liquids from the surface and bottom of the water without any capacity change owing to their hydrophobicity and oleophilicity. These features of the nanocomposite make it a potential sorbent for the cleaning of oils and oil derivative organic contaminants from the environment.