The potential of DBD plasma pretreatment for the isolation of micro- and nano-cellulose fibers from the walnut shells

Abstract

This study investigated the use of dielectric barrier discharge (DBD) plasma as a pretreatment to extract micro and nano-cellulose fibers from walnut shells (WS). The powdered WS was subjected to plasma at 18 and 20 kV before undergoing sodium hydroxide alkaline, sodium chlorite bleaching, or both alkaline and bleaching treatments. A control sample was also prepared without plasma treatment. The extracted cellulose was then analyzed for extraction efficiency, chemical composition, color, crystallinity index, FTIR, thermal properties, microstructure, and surface composition. The results showed that the plasma pretreatment reduced the cellulose extraction efficiency from ∼26 % to ∼22 % which was accompanied by a decrease in the C-C/C-H and C-OH/C-O-C bonds. The 20 kV plasma pretreatment prior to both alkaline and bleaching treatments resulted in the conversion of microfibrils into nanofibrils, with an average diameter of 80 ± 10 nm. These changes in the fiber structure were likely caused by the disruption of hydrogen-bonding interactions in the plasma-treated samples, leading also to a reduction in crystallinity index. The plasma-treated sample exhibited a different weight loss pattern below 100 °C compared with the control, originating from changes in water absorption. Overall, the study demonstrated that plasma pretreatment can successfully produce micro and nano-cellulose fibers from WS.