Abstract

The potential dependence of reaction product composition has been studied on high purity binary Cu-Ni alloys (10–40%Ni) in 0·5M sodium chloride solution at 25°C. The results show that the reaction products contain Ni concentrations in excess of those in the alloys at 0·00 V and below. The composition of solid reaction product films is more potential dependent than that of the overall reaction products. Controlling mechanisms are discussed.

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