Abstract

If it is assumed that the series electron of an atom polarises the core, then it has been shown by Born and Heisenberg that the polarisability α of the core in a given state may be calculated from the corresponding term value by means of the approximate formulae, where q is the quantum defect, δν is the difference between the term and the corresponding hydrogen term, R is the Rydberg constant in cm.−1, α1 is the radius of first hydrogen orbit, n is the principal quantum number, k is the azimuthal quantum number, For terms with small quantum defect either of the formulae (1) and may be used, but for terms with large quantum defect (1) gives a higher degree of accuracy.

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