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https://doi.org/10.1016/0040-4020(68)88121-9
Copy DOIJournal: Tetrahedron | Publication Date: Jan 1, 1968 |
Citations: 22 |
Photochemical behaviour of 1,2,3-triphenylaziridine has been investigated. Irradiation in alcoholic solvents induces a novel type of alcoholytic cleavage of the aziridine ring to give benzaldehyde acetals and N-benzylaniline. Competitively, fragmentation occurs to give rise to benzalaniline and phenylcarbene, the latter being trapped with alcohols as alkyl benzyl ethers. Photolysis in cyclohexene affords a 1,3-cycloaddition product, 1,2,3-triphenyloctahydroisoindole as a mixture of two stereoisomers.
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