Abstract
The [11.9]Ω = 3/2 ← X (2)Π(3/2)(0,0) and (1,0) bands of platinum monofluoride, PtF, have been recorded field-free and in the presence of a static electric field. The (19)F(I = 1/2) and (195)Pt(I = 1/2) magnetic hyperfine interactions have been analyzed and compared with predicted values obtained using atomic information and a proposed molecular orbital correlation diagram. The optical Stark shifts were analyzed to produce the permanent electric dipole moments, μ(el), of 2.47(11)D and 3.42(6)D for the [11.9]Ω = 3/2 and X (2)Π(3/2)states, respectively. The observed trend in μ(el) for the PtX (X = C,N,O,S and F) series is discussed and a comparison with IrF made.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
