Abstract
AbstractTwo novel isomers of BeO4 with the structures OBeOOO and OBe(O3) in the electronic triplet state have been prepared as well as the known disuperoxide complex Be(O2)2 in solid noble‐gas matrices. We also report the synthesis of the oxygen‐rich bis(ozonide) complex Be(O3)2 in the triplet state which has a D2d equilibrium geometry. The molecular structures were identified by infrared absorption spectroscopy with isotopic substitutions as well as quantum chemical calculations.
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