Abstract
The complex OD stretching vibrational Raman profile of 1-propanol (OD) in the gas phase has been analysed with the aid of a quantum mechanical calculation model based on the assumption of an intramolecular interaction between the stretching vibrational and torsional motions of the OD group. An assignment of the three band components caused by rotational isomerism in the molecule has been possible. The transition of the profile from triplet to singlet structure with increasing temperature could be attributed to vibrational transitions in torsionally excited states.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
