Abstract

The effect of iron and manganese concentration on the morphology of complex intermetallics and their influence on the mechanical properties and microstructure has been studied in an Al-16.67 wt. % Si alloy with three content of iron (0.4, 1.2, 1.8 wt.%), and two different content of manganese, i.e. 0.6 and 0.9 wt.%. The intermetallic compounds are formed at high iron contents or at high concentrations of manganese with low iron. The microstructural investigation by Clemex software showed that the biggest intermetallic size reached the surface area of 12750 μm2, when the amount of iron was increased from 1.2% to 1.8% wt.%. It was also showed that the volume fraction of intermetallic compounds increases as the iron and manganese content increases. Formation of complex intermetallic phases with iron adversely affects tensile strength decreasing from 229MPa with 0.4 wt.% of iron to 187MPa when iron content was increased to 1.8 wt.%.

Highlights

  • Iron is a common impurity in aluminium and its alloys that is not readily removed and may cause adverse effects to ductility and castability, in Al-Si based casting alloys

  • The solid solubility of iron in aluminium is very low with the result that most iron forms intermetallic compounds, the nature of which strongly depends on other present impurities or alloying elements [1,2]

  • Further elemental analysis by energy dispersive X-ray spectroscopy (EDX) indicated that the average composition was well consistent with the nominal composition

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Summary

Introduction

Iron is a common impurity in aluminium and its alloys that is not readily removed and may cause adverse effects to ductility and castability, in Al-Si based casting alloys. MJoM Vol 16 (1) 2010 p.11-24 increasing the amount of iron from a critical percentage, the ß-FeSi5Al intermetallic inevitably would be formed. This type of intermetallic has the most significant effect on the mechanical properties of Al-Si alloys. It especially decreases ductility because this compound tends to form thin platelets which are very brittle and have substantially low bond strength with the matrix. Platelets and needles of ß intermetallic have the main negative effects on fluidity, castability, and dendrites channel feeding of the alloy [3] causing unsoundness of castings [4]

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