The Morphological Characteristics of Authigenic Pyrite Formed in Marine Sediments

Abstract

Pyrites are widely distributed in marine sediments, the morphology of which is applied as a proxy to infer the redox conditions of bottom water, and identify diagenetic stages and hydrocarbon leakage activities. In this review, the methods used for the morphological study of pyrite are summarized. The textural and size characteristics of euhedral pyrite and pyrite aggregates, as the formation and evolution mechanism of pyrite are discussed for their significance in reconstructing the geochemical environment. The morphological study of pyrite includes shape observation, size estimation, and surface feature analysis. Scanning electron microscope and optical microscope are the main methods for morphological observation; transmission electron microscope and scanning tunneling microscope are applicable to observe nanoscale morphological structures and crystal growth on the crystal surface, and X-ray computed tomography is capable of measuring pyrite size distribution at the scale of a micrometer. Under the marine sedimentary condition, the single crystal of pyrite appears in cube, octahedron, dodecahedron, and their intermediates, the size of which ranges from several nanometers to more than 100 µm. The morphology of euhedral pyrite is controlled by temperature, pH, the chemical composition of interstitial water, etc., and might have been experienced in later reformation processes. The pyrite aggregates occur as framboid, rod-like, fossil-infilling, etc., characterized by the comparatively large size of several microns to several millimeters. It is found that certain textures correspond with different formation mechanisms and geochemical environments. Particularly, under special geological conditions, for instance, the methane leakage and/or decomposition of gas hydrate, pyrite is anomaly enriched with morphological textures of massive framboid cluster, rod-like aggregates, etc., and framboid is found with a large mean diameter (>20 µm) and standard deviation (>10 µm). These typical features can be employed to ascertain the position of the paleo sulfate methane transition zone (SMTZ).