Abstract
The molecular structure of gaseous germyl monothioacetate has been determined by electron diffraction. The only isomer present has the germyl group bonded to sulphur; the non-bonded Ge ⋯ O distance is substantially less than the sum of van der Waals radii for germanium and oxygen. Principal bond lengths and angles (ra) are: r(Ge–S) 223.3(4), r(C–S) 176.5(7), r(CO) 122.4(8), and r(C–C) 149.3(10) pm; GeSC 96.7(4), SCO 124.1(10), and CCO 116.4(13)°. The heavy-atom skeleton is almost planar, with the Ge–S and CO bonds arranged cis to one another.
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