Abstract
Chalcopyrite leaching has attracted much attention in both research work and industrial implementation due to its low cost. However, the slow Cu leaching rate during chalcopyrite dissolution process limits its wide application. This paper investigated the influence of mechanical activation on chalcopyrite leaching. The results showed that co-grinding of chalcopyrite and oxidants (i.e. Fe2(SO4)3·xH2O) stimulated solid-state reactions to form dissolvable copper sulfate, thereby increasing Cu extraction rate significantly. The reactions gradually proceeded with the increase of grinding time and speed, as well as the amount of oxidant. After activation, more than 98% of chalcopyrite was extracted in pH1.0 sulfuric acid maintained at 348K for 1.5h, significantly greater than that without activation, indicating a promising strategy for high efficient chalcopyrite leaching.
Published Version
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