Abstract

The mass spectra of some per- O-acetylaldono- and per- O-acetyldeoxyaldononitriles have been recorded. The major fragmentation-pathways are discussed in terms of the application of electron-impact mass-spectrometry to structural studies of aldoses. Both acetyl and deuterium-labelled acetyl derivatives are included. The spectra are useful in verifying the position of the deoxy group(s) of deoxyaldoses.

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