Abstract
ESR has been used to investigate the low temperature reaction between atomic hydrogen and polymethacrylate (PMA), polymethyl methacrylate (PMM), polydimethylsiloxane (PDMS), polypropylene (PP) and polyvinylacetate (PVA). The rate constants of the reactions H+RH→H 2+R (1), and H+R→molecular products (2) have been determined for the range 77–220°K. The kinetics are explained for reaction (1) by the tunneling effect.
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