Abstract
Free radical polymerization kinetic in a bulk for three diallyl phthalate isomers - diallyl orthophthalate, diallyl isophthalate and diallyl terephthalate was investigated in a temperature range from 50 to 70 °C initiated with dicyclohexan peroxydicarbonate as initiator at three different initiator concentrations. Conversion points were measured using Fourier Transform Raman measurements. A new kinetic model for polymerization of three diallyl phthalate isomers was developed. It demands the inclusion of only two new kinetic parameters k DegC and k pc which were obtained as a ratio k DegC /k pc from an additional set of experiments conducted. Computed conversions from the proposed kinetic model show good agreement with the conversion and molecular weight measured data for all three investigated diallyl phthalate isomers.
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