The interaction between volcanic gases and tephra: Fluorine adhering to tephra of the 1970 hekla eruption

Abstract

The mass distribution and sorting of tephra produced in the plinian phase of the 1970 Hekla eruption was controlled by the particle size distribution, the height of the eruption column, and velocity of transport. Near the volcano the mass distribution of soluble fluorine was controlled by particle size of the deposits, but approaches the mass distribution of the tephra at longer distances. Adsorbed soluble fluorine reaches a maximum at a distance from the volcano determined by the velocity of the transporting medium. SEM studies show the soluble fluorine to be chemically adsorbed on the surface of tephra particles. The adsorption is shown by experiment to occur at temperatures below 600°C in the cooling eruption column. Evaluation of reactions in the eruption column leads to the conclusion that formation of water soluble compounds adhering to tephra is principally controlled by environmental factors and to a lesser degree by the composition of the volcanic gas phase.