Abstract

This study aims to determine the effect of lime and nitrogen fertilizer on soil acidities characters, growth and nitrogen uptake of corn in total reclaimed of potential acid sulphate soil. A pot experiment with a completely randomized design arranged in factorial with three replications was conducted in the Greenhouse of Indonesian Swampland Agricultural Research Institute (ISARI) from August 2014 to December 2015. The first factor was the rate of lime as dolomite: (i) 25 t ha-1, and (ii) 37.5 t ha-1. The second factor was the type of nitrogen fertilizer: (a) control (without N), (b) nitrogen 115 kg ha-1, (c) chicken manure 6 t ha-1 (the total N content is 1.98%) and (d) nitrogen 57.5 kg ha-1 + 3 t ha-1 chicken manure. Urea (N content is 39.76%) was used for fertilization. The observed variables were the soil acidities properties (pH, Electrical conductivity/EC, available-H, available-Al) before, after total reclamation, and at the maximum vegetative stage of corn, plant growth and uptake of shoot nitrogen. The results showed that the process of consecutively aeration-leaching of the potential acid sulphate soils able to increase the soil pH, declining the EC value, as well as availabe bases, available-H, available-Al and the content of pyrite. The application of dolomite increased soil pH, EC, and available-H, while available-Al decreased, its effect was more pronounced in higher rate. Application of dolomite 25 t ha-1 and 37.5 t ha-1 respectively increased soil pH from 3.29 to 4.36 and 4.87, EC from 0.70 mS cm-1 to 1.51 mS cm-1, available-H from 1.30 cmol(+) kg-1 to 2.68 cmol(+) kg-1 and 1.44 cmol(+) kg-1 and decreased available-Al from 14.04 cmol(+) kg-1 to 4.71 cmol(+) kg-1 and 2.66 cmol(+) kg-1. However, these rates was not able to neutralize the existing acidity due to the acidity still being produced out of remaining pyrite which was still in active stages. It was showed increasing pH soil followed by EC. The interaction between the application of dolomite and nitrogen fertilizer is significantly influenced plant height and shoot N uptake. The highest plant height and shoot N uptake were 112 cm and 267.69 mg plant-1 respectively, were obtained in application dolomite 25 t ha-1 combined with nitrogen 57.5 kg ha-1 plus chicken manure 3 t ha-1. The highest of averages shoot and root dry weight was 20.97 g and 6.40 g respectively which were obtained in the application of nitrogen 57.5 kg ha-1 + chicken manure 3 t ha-1.

Highlights

  • Potential acid sulphate soils are soils containing iron sulphide mainly pyrite (FeS2) that stable in anaerobic condition within the pH tending to be neutral

  • Because pKa of Aluminum is 5, while in the research oxidation-leaching resulted in soil pH 3.29, the increase in pH was caused by the consumption of protons

  • The highest plant growth was obtained on a combination of nitrogen 57.5 kg·ha-1 and chicken manure 3 t·ha-1 at a dose of dolomite 25 t·ha-1 and 37.5 t·ha-1

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Summary

Introduction

Potential acid sulphate soils are soils containing iron sulphide mainly pyrite (FeS2) that stable in anaerobic condition within the pH tending to be neutral. There are two approaches to utilize the potential acid sulfate soil, namely (1) limiting the oxidation of pyrite and prevent acidity by maintaining groundwater levels (suitable for rice), (2) maximizing the oxidation of pyrite by drying and wetting intensively and discharging oxidation products through leaching (Arunin et al, 2009). The potential acid sulphate soil can be used for upland crops after a “total reclamation” is applied, means that maximizing the aeration and leach out of its oxidation product untill the remaining pyrie not active anymore. An important step in the process of reclamation through oxidation-leaching is to decrease soil acidity and toxic elements through leaching of pyrite oxidation products. After the reclamation process, it is necessary to neutralize the residual acid left in the soil

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