Abstract
Hydrothermal syntheses leading to clathrasils were carried out under high pressures of different gases (CO 2 , SF 6 ), employing organic or organometallic molecules as structure-directing agents (SDAs). The type of clathrasil formed depends on the chosen SDA and on the specific gas used. The gas molecules as well as the SDA molecules are occluded in the cages of the clathrasils, as proven by different methods. The gases act either as “co-SDAs” or can themselves take the role of a primary SDA, when no other SDA molecules are present. Here, we report about the influence of high pressures of CO 2 and of the inert gas SF 6 .
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
