The Influence of Activated Carbon Particle Size on the Properties and Performance of Polysulfone Composite Membrane for Protein Separation

Abstract

The superiorities provided by polymeric composite membranes in comparison to the original membrane have generated increased attention, particularly in the field of protein separation applications. This work involved the fabrication of polysulfone composite membranes using variable loadings of activated carbon particle sizes, namely, 37 µm, 74 µm, 149 µm, and 297 µm. The membranes were fabricated via the phase-inversion method, employing water as the coagulant. In this study, the impact of the AC powder particle sizes on membrane morphology, water contact angle, porosity, average pore size, molecular weight cutoff, pure water flux, and protein rejection was examined. Different membrane morphologies and properties were achieved by incorporating a variety of AC particle sizes. A porous membrane with the maximum pure water flux was generated by the loading of finer AC particles. Concurrently, protein rejection is increasing as a result of the use of AC particles as an infill in the composite membrane. In comparison to all fabricated membranes, the AC filler with a particle size of 149 µm exhibited the highest rejection of the lysozyme protein, reaching up to 73.9%, with a relatively high water permeability of 33 LMH/Bar. In conclusion, this investigation provides recommendations for the selection of AC particle sizes for protein separation in conjunction with PSF ultrafiltration membranes.