Abstract
The reaction between allene and hydrogen over unsupported palladium, platinum, iridium, rhodium, ruthenium, and osmium catalysts has been investigated in a static constant volume system between 70 and 149 °C for a wide range of reactant ratios. The orders of reaction with respect to hydrogen and allene were one and zero, respectively, and temperature independent. The overall apparent activation energies for unsupported platinum, iridium, palladium and rhodium were 17.7, 9.1, 6.4, and 17.4 kcal/mol, respectively. The catalytic activities of the unsupported metals were in the sequence Pd > Ir > Rh > Pt > Ru, Os. Selectivity was highest with palladium and rhodium, and least with iridium. The polymerization was highest with platinum and least with indium.
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