Abstract
The reaction of α,β,γ,δ-tetraphenylporphinato-oxochromium(IV)[(TPP)CrO] with α,β,γ,δ-tetraphenylporphinato-iron(II)bis(piperidine) in toluene results in the formation of the mixed-metal complex (TPP)CrIII–O-FeIII(TPP) characterised by chemical reactions and magnetic measurements [the metal ions are antiferromagneticlly coupled Fe (S= 5/2)-Cr (S= 3/2)]; similar µ-oxo compounds having dissimilar porphyrin ligands on each metal have also been prepared.
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