Abstract
The first total synthesis of (+)-rogioloxepane A is described. The α,ω- trans-disubstituted oxepene skeleton was stereoselectively constructed via cyclization of the hydroxy epoxide promoted by the (Bu 3Sn) 2O/Zn(OTf) 2 system. The proposed configurations of 6 R and 13 R were confirmed through this synthetic study.
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