Abstract
A new sodium tetrafluoroborate bridged neutral helical coordination polymer, formulated as [Na(1,10-phenanthroline)BF 4] n , has been synthesized and characterized. X-ray single crystal determination reveals that the Na(I) center has hexa-coordinate distorted octahedron coordination geometry and BF 4 − anion serves as a multidentate bridging ligand coordinated to three adjacent sodium cations forming an infinite one-dimensional single-strand helix. To the best of our knowledge, the title complex is an unprecedented type of helical structure in which only coordinated alkali metal sodium(I) and bridging tetrafluoroborate are present.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.