One-dimensional helical coordination polymers of cobalt(II) and iron(II) ions with 2,2′-bipyridyl-3,3′-dicarboxylate (BPDC 2−)

Abstract

One-dimensional (1-D) helical coordination polymers, [M II(H 2O) 3(BPDC)] n · nH 2O (M = Co ( 1), Fe ( 2)), have been prepared by the self-assembly of cobalt(II) and iron(II) ions, respectively, with 2,2′-bipyridyl-3,3′-dicarboxylic acid (H 2BPDC) in an aqueous solution. X-ray crystal structures of compounds 1 and 2 show that each metal ion displays a distorted octahedral coordination geometry including three water oxygen atoms, one oxygen atom of the carboxylate of a BPDC 2− belonging to the adjacent metal ion and two nitrogen atoms from the BPDC 2− acting as a chelating ligand. In 1 and 2, one carboxylate oxygen atom of coordinated BPDC 2− binds to the neighboring metal ion, which give rise to 1-D helical coordination polymers. The helical chains of 1 and 2 are linked by the hydrogen bonding interactions between the carboxylate oxygen atom of the BPDC 2− ion belonging to a chain and the water molecule of the adjacent helical chain, which lead to 2-D networks extending along the ab plane. The supramolecules 1 and 2 show isomorphous structures regardless of the metal ions.