The first report of a tetra-azide bound mononuclear cobalt(iii) complex and its comparative biomimetic catalytic activity with tri-azide bound cobalt(iii) compounds

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Three new azide-bound cobalt(iii) complexes derived from three different triamines with extensive hydrogen bonded supramolecular chain structures and the role of their structural factors in oxidative coupling of o-aminophenols have been reported.