Abstract

In the present study we evaluate the feasibility of using untreated industrial sewage sludge by liming before use as a fertilizer, produced in Pakistan. In a pots experiment, limed industrial sewage sludge (LSW) and non-limed sewage sludge (NLSW), were amended with soil separately and grown sorghum. After maturity, the sorghum grains were analysed for total contents of potentially toxic metals (TPTM), As, Cd, Cr, Cu, Ni, Pb and Zn. The proportion of different mobility fractions of each element in LWS and NLSW, a modified BCR sequential extraction procedure (Community Bureau of Reference) and single extractions with mild extractants (deionized water and CaCl2) were used. In LSW, the availability of most of the elements under study was reduced, probably due to the increased pH of soil, while this was the reverse in the cases of Cd and Cu, their mobility was slightly increased by lime-treated sludge. The sorghum grains grown in LSW have low level As, Cr, Ni, Pb and Zn as compared to grains grown in NLSW, except Cu and Cd, which, however, never exceeded legal limits. Thus the research showed that liming, by augmenting soil alkalinity, allows a safe agricultural use even of industrial sludge, which is environmentally hazardous for its great content of heavy metals.

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