Abstract

By the use of levitation melting, an experimental technique has been developed to measure the rate of free evaporation of liquid metal out of contact with any contaminating support materials.The evaporation of liquid iron under vacuum in the range 1687 to 1840°c has been studied. The rate in g·cm−2.sec-1 is given bylog Φ = − 17,308/T + 6.0522 ± 0.0371From this, the vapour pressure of liquid iron in mm Hg was determined asLog P°Fe = − 17,750/T + 8.2936 ± 0.0364The rate of evaporation of copper from iron-copper droplets between 1700 and 1760°C was about 50-70 per cent of the value expected if the loss was controlled entirely by the rate of evaporation from the surface. Résumé Une technique de mesure du taux d' évaporation libre des métaux à l' état liquide vient d'être mise au point. La lévitationen phase liquide a été utilisée pour éliminer la contamination du métal au contact d'un creuset.L' évaporation sous vide du fer liquide a été étudiée dans l'intervalle de tempérapture 1687 à 1840°C. Le taux d' évaporation en g·cm−2·sec−1 estlog Φ = − 17,308/T + 6.0522 ± 0.0371À partir de cette relation, la tension de vapeur du fer liquide en mm Hg á été determinée:Log P°Fe = − 17,750/T + 8.2936 ± 0.0364En outre, il a été trouvé que de 1700 è 1760°C le taux d' évapouration du cuivre de goutte lettes fer-cuivre se chiffre entre 50 et 70 pour-cent du taux calculé d'après l'hypothèse d'une cinétique réglée par l' étape d' évapouration en surface.

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