Abstract

Di-tin hexaphenyl has been burnt in an aneroid combustion calorimeter. The standard enthalpy of combustion was ΔH c o = − (4846.0 ± 2.0) kcal mol −1, which yields a standard enthalpy of formation, ΔH f o(Sn 2Ph 6,c) = (157.8 ± 2.0) kcal mol −1. A self-consistent mean bond energy scheme has been constructed for the organo-metallic compounds of Group IV and some carbon-metal mean bond dissociation energies have been calculated.

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