Abstract

Mercury diphenyl has been burnt in a static bomb combustion calorimeter. The standard enthalpy of combustion is Δ H ° o = (−1537.8±1.9) kcal mol −1 , which yields a standard enthalpy of formation Δ H ° f (HgPh 2 ,c) = (67.6±1.9) kcal mol −1 . A self-consistent bond energy scheme has been constructed for organo-mercury compounds and some associated bond dissociation energies have been calculated.

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