Abstract
Abstract An electrochemical synthetic method has been developed to effect the one-step preparation of transition metal xanthates and dithiocarbamates by oxidation of the metal in an acetone solution of ethyl dixanthogen or tetramethylthiuram disulphide. Results are presented for O-ethylxanthate and N,N′-dimethyldithio-carbamate complexes of iron(III), cobalt(III), nickel(II) and copper(I, II).
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