The effects of Ta on the stress rupture properties and microstructural stability of a novel Ni-base superalloy for land-based high temperature applications

Abstract

A novel polycrystalline Ni-base superalloy was developed for land-based high temperature applications, such as isothermal forging dies and industrial gas turbines. The alloy possessed surprisingly high stress rupture life of 52h at 1100°C/118MPa which is comparable to the first generation single crystal (SC) superalloy and exhibited good microstructural stability. The effects of Ta addition on the phase change, stress rupture properties and microstructural stability of the alloy were investigated. The results indicated that Ta is a γ′-former and promotes the formation of eutectic γ′. The alloys with ∼7vol.% eutectic γ′ possess higher stress rupture life at 1100°C/118MPa than the alloys with higher ∼20vol.% eutectic. However, ∼20vol.% excessive eutectic phases will enhance the stress rupture life at intermediate temperature of 760°C for 686MPa but weaken high temperature stress rupture properties. The (Al+Ta) content over 14.4at.% led to the formation of large amounts of eutectic γ′ and exceeded the solubility of W and Mo in the residue liquid pool, which then promoted the precipitation of primary α-(W,Mo) and M6C phases. Tantalum was also found as a strong MC carbides forming element. The order of ability to form monocarbide decreased from NbC to TaC to TiC. 6Al–0Ta (wt.%) alloys possessed good microstructural stability with no harmful topologically close-packed (TCP) phases being observed after thermal exposure at 850°C/3000h, 900°C/1000h. Only trace amounts of secondary plate-like M6C carbides appeared in Ta-free and 5Al–4Ta (wt.%) alloys at 1100°C/100–500h. However, excessive Ta addition will destabilize the alloy and large amounts of secondary plate-like M6C carbides precipitated after thermal exposure at 1100°C. The transmission electron microscopy (TEM) and selected area electron diffraction (SAED) results showed the existence of the plate-like M6C carbides.