Abstract

Biogas is produced by the digestion of organic waste by anaerobic bacteria. However, the application of raw biogas is not effective because it consists of impurities such as carbon dioxide (CO2), hydrogen sulfide (H2S), water vapor (H2O), and other impurity gases. Physical Adsorption is the simplest method of immobilization of biomolecules such as CO2 which is attached to the surface through the weak bonds like van der Waals forces. One of the physical adsorption means to reduce CO2 levels in biogas is to use brick powder. Increasing of brick powder adsorbent mass caused the decrease of CO2 concentration in the biogas purification. Brick is a porous material containing SiO2 - Al2O3, so it has the ability to form Van der Waals bonding forces with CO2. The goal of this research is to determine the efficiency of brick powder as a purification adsorbent to reduce of CO2 levels using the 23 factorial design method. The application of 200 and 400 grams brick powder adsorbents, with the biogas flow rate of 1 and 2 liters/minute, was researched at intervals of 5 and 20 minutes, for the CO2 concentration data and heating values of biogas. Gas Chromatography (GC) was used to determine the concentration of adsorption gases, especially CO2 and CH4. The results showed that the biggest efficiency reduction in CO2 concentration is 59.28%.

Highlights

  • IntroductionA lot of renewable energy can be obtained, such as: solar energy, wind energy, geothermal energy, and biomass energy [1]

  • Renewable energy production is a big issue in the world

  • The equipment used in this research are Gas Chromatography (GC) at Greenhouse Gas Laboratory (Balingtan, Pati, Center Java), rotap rocker as a sieve to adjust grain size, digital balance to measure the mass of adsorbent, tedlar bag to accommodate post-purification gas samples, flowmeter to regulate flow rate, stopwatch to measure purification time, polyurethane hose for biogas distribution lines, distribution tubes for storing pressurized biogas, purifying equipment and biogas compression for transferring biogas from digesters

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Summary

Introduction

A lot of renewable energy can be obtained, such as: solar energy, wind energy, geothermal energy, and biomass energy [1]. Biomass is the main energy resource for biogas as a renewable energy, being mostly found in agricultural residues, livestock manure, and others [2]. Restaurants, parks, and wastes from industry [3], [4]. Biogas is produced from anaerobic bacterial digestion of degraded organic waste [5]. The composition of biogas consists of 35-75 % methane, 25-65 % carbon dioxide, 1-5 % hydrogen, and tracer of water vapor, ammonia, and hydrogen sulfide. Poor biogas quality (CH4 / CO2 < 1) exacerbates damage to the atmosphere [6]. Purification techniques are used to clean and enhance biogas into biomethane which can replace natural gas [7]

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