Abstract
With the development of modern medical implants, there are significantly increasing demands for personalized prosthesis. Corrosion-resistance and dense cobalt alloy specimens have been successfully fabricated by laser metal deposition. The relationship between specific energy density, microstructure and corrosion resistance of the specimens is investigated. The results show that higher specific energy density promotes the formation of columnar grain and leads to coarse grain size. The evolution and distribution of deposited microstructure from bottom to top are summarized in a metallographic sketch. The corrosion current of deposited specimens increases from 2.071 × 10−6 A/cm2 to 6.86 × 10−5 A/cm2 and rapidly drops to 9.88 × 10−7 A/cm2 with increase of specific energy density from 318.8 J/g to 2752.3 J/g. The columnar and equiaxed structure of deposited specimens have lower corrosion current than mixed structure due to finer grain and less Mo segregation. The deposited have low level metal released because of passive film. The passive film have different formation routes in Hank’s solution and acidic saliva. The specific energy density has an important effect on the microstructure of deposited, which improves corrosion resistance and life span in implant.
Highlights
Cobalt-chromium-molybdenum (CoCrMo) alloy is widely used in removable partial dentures and medical implant such as metal frames, customized abutments, crowns, bridges, hips, knees and ankles [1,2]
Columnar grain and equiaxed grain are the predominant microstructure of the deposited specimens, in addition, cellular grain at the bottom
The major results are as follows: Cr makes a major contribution to passive film formation
Summary
Cobalt-chromium-molybdenum (CoCrMo) alloy is widely used in removable partial dentures and medical implant such as metal frames, customized abutments, crowns, bridges, hips, knees and ankles [1,2]. Around 10% of joint transplant patient total hip arthroplasty require revision surgery [3]. This proportion has been continuously increasing with the younger and more physically active group at a higher revision rate. These revisions are caused by a mismatch between implant and bone geometry and corrosion of implant. Geometric accuracy is improving as AM techniques continuously develop
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