The effect of rare earth oxides on the pressureless liquid phase sintering of α-SiC

Abstract

Silicon carbide (SiC) ceramics have been fabricated by pressureless liquid phase sintering with Al2O3 and rare-earth oxides (Lu2O3, Er2O3 and CeO2) as sintering additives. The effect was investigated of the different types of rare earth oxides on the mechanical property, thermal conductivity and microstructure of pressureless liquid phase sintered SiC ceramics. The room temperature mechanical properties of the ceramics were affected by the type of rare earth oxides. The high temperature performances of the ceramics were influenced by the triple junction grain boundary phases. With well crystallized triple junction grain boundary phase, the SiC ceramic with Al2O3–Lu2O3 as sintering additive showed good high temperature (1300 °C) performance. With clean SiC grain boundary, the SiC ceramic with Al2O3–CeO2 as sintering additive showed good room temperature thermal conductivity. By using appropriate rare earth oxide, targeted tailoring of the demanding properties of pressureless liquid phase sintered SiC ceramics can be achieved.