Abstract

Chalcopyrite and wurtzite CuInS2 (CIS) nanomaterials were synthesized from Cu[Formula: see text], In[Formula: see text], thiourea with or without triethanolamine (TEA) by simple hot injection method at low temperature. The effect of synthesis duration on the various properties of the synthesized CIS nanomaterials was studied. It shows that for chalcopyrite CIS, the optimal synthesis duration is 60 min and the synthesized nanomaterial is in spherical shape with diameter of about 90 nm. However, for the wurtzite CIS, the optimal synthesis duration should reach 150 min and the synthesized nanomaterial looks like nanoplate with thicknesses of [Formula: see text]10 nm and diameters near 100 nm. The photovoltaic characteristics of two types of nanomaterials are quite different. This study may contribute to the synthesis of CIS nanomaterials at low temperatures.

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