Abstract
Vineyards exposed to wildfire generated smoke can produce wines with elevated levels of lignin derived phenols that have acrid, metallic and smoky aromas and flavour attributes. While a large number of phenols are present in smoke affected wines, the effect of smoke vegetation source on the sensory descriptors has not been reported. Here we report on a descriptive sensory analysis of wines made from grapes exposed to different vegetation sources of smoke to examine: (1) the effect vegetation source has on wine sensory attribute ratings and; (2) associations between volatile and glycoconjugated phenol composition and sensory attributes. Sensory attribute ratings were determined by a trained sensory panel and phenol concentrations determined by gas chromatography-mass spectroscopy. Analysis of variance, principal component analysis and partial least squares regressions were used to evaluate the interrelationships between the phenol composition and sensory attributes. The results showed that vegetation source of smoke significantly affected sensory attribute intensity, especially the taste descriptors. Differences in aroma and taste from smoke exposure were not limited to an elevation in a range of detractive descriptors but also a masking of positive fruit descriptors. Sensory differences due to vegetation type were driven by phenol composition and concentration. In particular, the glycoconjugates of 4-hydroxy-3-methoxybenzaldehyde (vanillin), 1-(4-hydroxy-3-methoxyphenyl)ethanone (acetovanillone), 4-hydroxy-3,5-dimethoxybenzaldehyde (syringaldehyde) and 1-(4-hydroxy-3,5-dimethoxyphenyl)ethanone (acetosyringone) concentrations were influential in separating the vegetation sources of smoke. It is concluded that the detractive aroma attributes of smoke affected wine, especially of smoke and ash, were associated with volatile phenols while the detractive flavour descriptors were correlated with glycoconjugated phenols.
Highlights
Wines produced from vineyards exposed to bushfire smoke often have unpalatable levels of smoke related attributes including smoky, metallic, bitter, ash and medicinal flavour and aroma sensory descriptors [1,2]
The sensory profile of smoke affected wines is thought to be closely related to the volatile phenol composition; it has been recently shown that glycoconjugated phenols may deconjugate to the volatile forms in the mouth during tasting [2] and may have direct impact on the flavour profile [8]
Merlot wines made from grapes exposed to smoke emissions from the three vegetation fuel types in this study were significantly higher in putative taint phenols than unsmoked control wines [3]
Summary
Wines produced from vineyards exposed to bushfire smoke often have unpalatable levels of smoke related attributes including smoky, metallic, bitter, ash and medicinal flavour and aroma sensory descriptors [1,2]. These detractive sensory descriptors in wine, known as smoke taint, have low consumer acceptance and are due to the uptake of smoke-borne lignin derived phenols into grapes [3], which remain in finished wines [4]. While each phenol has a characteristic sensory threshold in wine, a synergistic effect is expected to occur where a combination of phenols below their respective threshold concentrations have a significant effect on the sensory properties [9,10]
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