Abstract

Recently, two-dimensional hybrid organic–inorganic perovskites (2D-HOIPs) have emerged in popularity due to ease of tunability in terms of the structure and properties. However, a systematic chemistry and physical description of cobalt-based system is lacking. In this study, we employ X-ray diffraction, Raman spectroscopy and electrochemical impedance spectroscopy (EIS) techniques to investigate the effect of the organic ligand length on the structural, vibrational, and electrical properties of A2CoCl4 [A = methylammonium (MA), ethylammonium (EA) and butylammonium (BA)] perovskite. Results from the measurements showed a noticeable difference and showed potential usage in future applications in the field of electronics.

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