The Effect of Heating Time on the Thermal Stability of Chrome-Tanned Leather

Abstract

Chrome tanning is an essential process to convert raw animal skin into leather, in which collagen, as the main structure of leather, is stabilized against degradation through cross-linking using chromium, consisting of two steps: penetration and basicity. However, the uptake of chrome in leather still needs to be improved. The purpose of this study was to find the best heating time in the chrome tanning process by thermal analysis. Pickled sheepskin was used as raw material for the chromium tanning process. The samples were varied into four categories: heated at the penetration stage of the tanning process (Initial Heating), heated at the basification stage of the tanning process (Final Heating), and heated both at the penetration and basification stage (Continuous Heating). In this study, the thermal stability of wet blue leather was evaluated by shrinkage temperature behavior (Ts), thermogravimetry analysis (TGA/DTG), and differential scanning calorimetry (DSC). The tanning efficiency was measured by Cr2O3 content. The results demonstrated that wet blue samples heated continuously shows better thermal characteristics. In conclusion, the results can be used for finding the best possible technique for the leather tanning process using chrome salts to gain thermal stability.