The distribution of manganese and iron between ilmenite and granitic magma in the �sumi Peninsula, Japan

Abstract

Manganoan ilmenite with a variable manganese content occurs as an early accessory constituent of granitic rocks in the Osumi Peninsula, southern Kyushu. Electron probe micro-analysis of a grain containing highest manganese gives the structural formula (Fe1.232+Mn0.812+) (Ti1.97) O6, if all of the manganese and iron are in the divalent state. The manganese content of manganoan ilmenite increases with an increase of the differentiation index of host rocks, however, the amount of ilmenite tends to decrease with the increase of the same index. The mode of occurrence of the ilmenite suggests that it is the first mafic mineral to precipitate from the magma. The average value of the distribution coefficient of manganese and ferrous iron between ilmenite and granitic magma is 5.5, if the Mn/Fe ratio of the granitic rocks represents that of granitic magma. The variation in the FeO and MnO contents against the differentiation index for granitic rocks of the Osumi Peninsula, and the value of the distribution coefficient, show that high manganoan ilmenite is stable in the most differentiated granitic rock of the Osumi Peninsula.