Abstract
The dipole moment function of the a 3Π state of CO is calculated using the multi-configuration self-consistent-field method of Wahl and Das. Only the dominant valence charge-transfer correlation configurations are mixed with the Hartree-Fock configuration since only the region between the classical turning points of the v = 1 vibrational level is considered. The calculated function does not agree with the shape of the fitted dipole moment function of Wicke et al. Configurations chosen on the basis of the model of optimized valence configurations do not determine an accurate dipole moment function for an open shell system.
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