Abstract

A pulse polarographic method is described for determining traces of nickel in cobalt, and its compounds, without separation. The detection limit in pyridine is as low as 1 p.p.m in metallic cobalt, and 0.25 p.p.m. in cobalt compounds, while in potassium thiocyanate these limits are decreased to 0.25 and 0.06 p.p.m., respectively. The method was applied to the analysis of synthetic and commercially available cobalt samples and showed satisfactory sensitivity at various nickel levels.

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