Abstract
Abstract The molecular structure of [Pd(acac)2(NHEt2)] was determined by means of X-ray diffraction. The crystal belongs to the monoclinic system: a=14.166(1), b=8.209(1), c=14.764(2) Å, β=100.75(1)°, space group P21/n, with Z=4. The structure was solved by the heavy-atom method and refined anisotropically by the least-squares procedure; R=0.067 for 3149 non-zero reflections. The geometry around the Pd atom is square-planar: one of the two (acac) ligands coordinates to the Pd atom by O,O′-chelation, and the other, by σ-bonding of the γ-carbon atom, while the diethylamine occupies the fourth coordination site. A weak intramolecular N–H···O hydrogen bond [2.962(10) Å] is observed.
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