Abstract

SYNOPSIS The study investigates the effect of prior corrosive exposure on crack growth resistance behaviour of thin sheet (3 mm thick) aluminium alloy 2024-T3 at slow strain rates. Compact tension specimens were exposed to standard corrosive environments that simulate accelerated atmospheric corrosion attack. TWo corrosive environments were considered - an exfoliation corrosion (EXCO) solution and a 3.5 wt% sodium chloride solution. The unloading compliance R-curves of the two-hour EXCO-exposed specimens revealed a significant degradation of approximately 11% in the crack growth resistance behaviour (Kcevalues) compared to the baseline (air-exposed) values. Furthermore, secondary intergranular crack formation was also revealed in the plastic zone ahead of, and adjacent to, the crack tip of these specimens; which formed during the crack growth resistance loading. It is postulated that the observed degradation of the Kce values of the EXCO-exposed material is due to hydrogen embrittlement since the exposure times for the EXCO evaluation were limited to ensure that uniform corrosion dominated; that is, significant penetration of corrosion damage and pitting due to localized corrosive attack did not occur. The sodium chloride-exposed specimens revealed a similar degradation (13%) after 24 hours exposure. However, slight intergranular corrosive attack and isolated pitting were observed on the exposed surfaces prior to crack growth resistance loading, resulting in notch effects that could assist in crack growth. Pitting and intergranular corrosion were, however, not observed at the pre-crack tip. The relative contributions of the notch effects and the hydrogen embrittlement during the degradation of the KR performance are, therefore, unclear. Keywords: corrosion, crack growth, aluminium alloy 2024-T3.

Highlights

  • The long-term service usage of the popular high-strength aluminium alloy 2024 in the aeronautical industry may lead to degradation in the alloy’s mechanical properties due to atmospheric corrosion exposure

  • After interruption of the KR testing at a crack mouth opening displacement of 3 mm, many secondary cracks parallel to the main crack front and on the exposed surface - were observed within the plastic zone

  • The fracture surface in this region was intergranular, while the fracture surface of the main crack front was ductile with a dimpled nature

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Summary

Introduction

The long-term service usage of the popular high-strength aluminium alloy 2024 in the aeronautical industry may lead to degradation in the alloy’s mechanical properties due to atmospheric corrosion exposure. Growth of the strengthening precipitates leads to a loss of coherency with the aluminium matrix; which is accompanied by the loss of the so-called coherency strains that hinder dislocation glide and provide strengthening. This may be followed by coarsening - in which the larger precipitates grow at the expense of the smaller ones (Ratke and Voorhees, 2002) - which will reduce the inter-precipitate spacing and aid in dislocation glide due to fewer obstacles hindering dislocation mobility.

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