Abstract
Some aspects of the coordination chemistry of phosphinoalkynes on polymetallic cluster frameworks are reviewed and illustrated with selected examples. Topics covered include the preparation of phosphinoalkynes, alkyne coordination, phosphine coordination, coordination in the absence of P–C bond cleavage, P–C bond cleavage and subsequent transformations of the resulting acetylide ligands, and the use of metal complexes of phosphinoalkynes as metalloligands in catalytic applications.
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