THE CONTRIBUTION OF AMMONIA, METALS AND NONPOLAR ORGANIC COMPOUNDS TO THE TOXICITY OF SEDIMENT INTERSTITIAL WATER FROM AN ILLINOIS RIVER TRIBUTARY

Abstract

Toxicity of Illinois River bulk sediment, sediment interstitial (pore) water and elutriates to the oligochaete Lumbriculus variegatus, fathead minnow (Pimephales promelas) and the amphipod Hyalella azteca was compared to determine the most representative aqueous fraction for toxicity identification evaluation (TIE) studies. Toxicity of pore water corresponded better than elutriates to bulk sediment toxicity. Subsequent TIE procedures conducted with the cladoceran Ceriodaphnia dubia indicated that ammonia, metals and nonpolar organic compounds (nonylphenols, polycyclic aromatic hydrocarbons, benzenes, long-chain hydrocarbons) were responsible for toxicity of the sediment pore water. Results of TIE manipulations also suggested that methods for recovering pore water that include filtration may eliminate, a priori, a major component of the sediment contaminants responsible for toxicity.